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Annual Review of Analytical Chemistry

Volume 10, 2017

Applications of the New Family of Coherent Multidimensional Spectroscopies for Analytical Chemistry

Abstract

A new family of vibrational and electronic spectroscopies has emerged, comprising the coherent analogs of traditional analytical methods. These methods are also analogs of coherent multidimensional nuclear magnetic resonance (NMR) spectroscopy. This new family is based on creating the same quantum mechanical superposition states called multiple quantum coherences (MQCs). NMR MQCs are mixtures of nuclear spin states that retain their quantum mechanical phase information for milliseconds. The MQCs in this new family are mixtures of vibrational and electronic states that retain their phases for picoseconds or shorter times. Ultrafast, high-intensity coherent beams rapidly excite multiple states. The excited MQCs then emit bright beams while they retain their phases. Time-domain methods measure the frequencies of the MQCs by resolving their phase oscillations, whereas frequency-domain methods measure the resonance enhancements of the output beam while scanning the excitation frequencies. The resulting spectra provide multidimensional spectral signatures that increase the spectroscopic selectivity required for analyzing complex samples.

Keyword(s): coherence transfer, DOVE, GRAPES, multiple quantum coherence, photon echo, sum frequency
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2017-06-12
2024-04-20
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Applications of the New Family of Coherent Multidimensional Spectroscopies for Analytical Chemistry
Annual Review of Analytical Chemistry 10, 45 (2017); https://doi.org/10.1146/annurev-anchem-061516-045349
/content/journals/10.1146/annurev-anchem-061516-045349
/content/journals/10.1146/annurev-anchem-061516-045349
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