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Annual Review of Physical Chemistry

Volume 63, 2012

Progress in Modeling of Ion Effects at the Vapor/Water Interface

Abstract

The behavior of halide salts at the vapor/water interface has been the focus of a tremendous amount of work in the past ten years. A molecular view of the interface has been introduced with the observation that large anions have some affinity for the interface, but a quantitative description of the driving forces that determine ion adsorption or repulsion at the interface is still missing. This review discusses recent developments that are based on classical and quantum-chemical molecular simulations as well as developments that are based on simple potential models.

Keyword(s): force fields, Hofmeister effects, molecular simulations, surface tension
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2012-05-05
2024-12-05
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/content/journals/10.1146/annurev-physchem-032511-143813
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Progress in Modeling of Ion Effects at the Vapor/Water Interface
Annual Review of Physical Chemistry 63, 401 (2012); https://doi.org/10.1146/annurev-physchem-032511-143813
/content/journals/10.1146/annurev-physchem-032511-143813
/content/journals/10.1146/annurev-physchem-032511-143813
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