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In situ research of cometary chemistry began when measurements from the Giotto mission at Comet 1P/Halley revealed the presence of complex organics in the coma. New telescopes and space missions have provided detailed remote and in situ measurements of the composition of cometary volatiles. Recently, the Rosetta mission to Comet 67P/Churyumov–Gerasimenko (67P) more than doubled the number of parent species and the number of isotopic ratios known for comets. Forty of the 71 parent species have also been detected in pre- and protostellar clouds. Most isotopic ratios are nonsolar. This diverse origin is in contrast to that of the Sun, which received its material from the bulk of the collapsing cloud. The xenon isotopic ratios measured in 67P can explain the long-standing question about the origin of terrestrial atmospheric xenon. These findings strengthen the notion that comets are indeed an important link between the ISM and today's solar system including life on Earth.
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