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Smart Responsive Polymers: Fundamentals and Design Principles
- Debashish Mukherji1,2, Carlos M. Marques3, and Kurt Kremer2
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View Affiliations Hide AffiliationsAffiliations: 1Stewart Blusson Quantum Matter Institute, University of British Columbia, Vancouver, British Columbia V6T 1Z4, Canada; email: [email protected] 2Max-Planck-Institut für Polymerforschung, 55128 Mainz, Germany; email: [email protected][email protected] 3Institut Charles Sadron, Université de Strasbourg, CNRS, 67034 Strasbourg, Cedex 2, France; email: [email protected]
- Vol. 11:271-299 (Volume publication date March 2020) https://doi.org/10.1146/annurev-conmatphys-031119-050618
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Copyright © 2020 by Annual Reviews. All rights reserved
Abstract
In this review, we summarize recent theoretical and computational developments in the field of smart responsive materials, together with complementary experimental data. A material is referred to as smart responsive when a slight change in external stimulus can drastically alter its structure, function, or stability. Because of this smart responsiveness, these systems are used for the design of advanced functional materials. The most characteristic properties of smart polymers are discussed, especially polymer properties in solvent mixtures. We show how multiscale simulation approaches can shed light on the intriguing experimental observations. Special emphasis is given to two symmetric phenomena: co-non-solvency and co-solvency. The first phenomenon is associated with the collapse of polymers in two miscible good solvents, whereas the latter is associated with the swelling of polymers in poor solvent mixtures. Furthermore, we discuss when the standard Flory–Huggins-type mean-field polymer theory can (or cannot) be applied to understand these complex solution properties. We also sketch a few examples to highlight possible future directions, that is, how smart polymer properties can be used for the design principles of advanced functional materials.
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