1932

Abstract

Photofragment spectroscopy is combined with imaging techniques and time-resolved measurements of photoions and photoelectrons to explore the predissociation dynamics of weakly bound molecules. Recent experimental advances include measurements of pair-correlated distributions, in which energy disposal in one cofragment is correlated with a state-selected level of the other fragment, and femtosecond pump-probe experiments, in some cases with coincidence detection. An application in which coincident measurements are carried out in the molecular frame is also described. To illustrate these state-selective and time-resolved techniques, we review two recent applications: () the photoinitiated dissociation of the covalently bound NO dimer on the ground and excited electronic states and the role of state couplings and () the state-selected vibrational predissociation of hydrogen-bonded acetylene dimers with HCl (acid) and ammonia (base) and the importance of angular momentum constraints. We highlight the crucial role of theoretical models in interpreting results.

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/content/journals/10.1146/annurev.physchem.040808.090441
2009-05-05
2024-06-20
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/content/journals/10.1146/annurev.physchem.040808.090441
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  • Article Type: Review Article
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