1932

Abstract

▪ Abstract 

Charge transport at conjugated polymer interfaces with metals and inorganic semiconductors is reviewed. Experiments on the equilibrium properties and DC current-voltage behavior of four specific classes of interfaces—metal–doped conjugated polymer, inorganic semiconductor–doped conjugated polymer, metal–intrinsic conjugated polymer, and metal–intrinsic conjugated polymer/electrolyte—are discussed. To facilitate this discussion, classic models of equilibration at ideal interfaces between electronic conductors and free-electron transport are introduced and their limitations discussed. Particular emphasis is placed on the charge distributions and interfacial potential profiles expected at various types of electroactive interfaces.

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/content/journals/10.1146/annurev.physchem.55.091602.094421
2004-06-01
2024-06-24
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  • Article Type: Review Article
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